Chemical Permeation Testing of Respirators for End Users Currently, first responder respirators are only evaluated for the effects of chemical permeation as part of testing specified by the NIOSH CBRN Statements of Standard. These requirements are applied in the NFPA 1981 standard on fire and emergency services SCBA and will appear in the new NFPA 1986 standard on technical and tactical operations respiratory equipment (SCBA). These criteria are also applied to air-purifying respirators and powered air-purifying respirators. Where respirators are worn externally as part of hazardous materials protective ensembles, no additional criteria for chemical protection are worn, especially for toxic industrial chemicals. In the next revision of NFPA 1994, a new class of ensemble will be established for high level of chemical protection for a non-encapsulating ensemble where SCBA will complete the dermal protection of the wearer.Intertek Testing Services has been awarded a contract from the Technical Support Working Group (TSWG) to develop a test method for evaluating selected respirators for their resistance to permeation against hazardous toxic chemicals other than chemical warfare agents. This project has arisen because respirators are increasingly being used externally as part of chemical protective ensembles and there are concerns that the chemical resistance of the materials used in the construction of the respirators do not have the same levels of chemical resistance as the protective clothing materials. Further, test methods used to evaluate protective clothing materials do not readily accommodate the non-flat, molded pieces used in the construction of respirators.The objective of this project is to develop test methodology and propose specific performance criteria related to how respirators resist the effects of toxic industrial chemicals that both permeate through respirator materials to enter the breathing air and cause inhalation exposures to the wearer and directly permeate through respirator facepiece materials to make direct contact with the wearer's skin for dermal exposures. The proposed test methodology involves a combination of whole respirator exposure with air quality measurements and use of skin simulants in a manner simulating use.This survey is intended to gather information from end users to help focus the direction of test method development and proposal of performance requirements. Question Title * 1. What is the principal function of the organization that you represent? Fire department Law enforcement Military Hazardous materials response Other (please specify) Question Title * 2. What is your position within your organization Management End user Purchasers Other (please specify) Question Title * 3. Do you or have you worn respiratory protective equipment on the outside of a chemical protective suit? Yes No I am unsure Question Title * 4. Which respirators do you own or use with chemical protective clothing? Open-Circuit, Self-Contained Breathing Apparatus (SCBA) Powered air-Purifying Respirators (PAPR) Air-Purifying Respirators (APR) Closed-circuit SCBA (rebreather) Other (please specify) Question Title * 5. What is the expected maximum use or mission time when using each type of respirator? < 30 minutes 30 to 60 minutes >60 to 120 minutes >120 to 240 minutes > 240 minutes Not applicable SCBA SCBA < 30 minutes SCBA 30 to 60 minutes SCBA >60 to 120 minutes SCBA >120 to 240 minutes SCBA > 240 minutes SCBA Not applicable PAPR PAPR < 30 minutes PAPR 30 to 60 minutes PAPR >60 to 120 minutes PAPR >120 to 240 minutes PAPR > 240 minutes PAPR Not applicable APR APR < 30 minutes APR 30 to 60 minutes APR >60 to 120 minutes APR >120 to 240 minutes APR > 240 minutes APR Not applicable Rebreather Rebreather < 30 minutes Rebreather 30 to 60 minutes Rebreather >60 to 120 minutes Rebreather >120 to 240 minutes Rebreather > 240 minutes Rebreather Not applicable An important part of the project is determine the types of threat conditions in which chemicals exposure of respirators occur and which chemicals should respirators be tested against. Chemicals that come in contact with your respirator may be both respiratory (inhalation) or skin absorption (dermal) hazards. The following questions are directed to this topic. Question Title * 6. How likely would you expect to be externally exposed to chemicals in the following ways? Very likely Likely Not likely Never By exposure to chemicals gases By exposure to chemicals gases Very likely By exposure to chemicals gases Likely By exposure to chemicals gases Not likely By exposure to chemicals gases Never By exposure to vapors generated by volatile liquids By exposure to vapors generated by volatile liquids Very likely By exposure to vapors generated by volatile liquids Likely By exposure to vapors generated by volatile liquids Not likely By exposure to vapors generated by volatile liquids Never By exposure to liquid splashes By exposure to liquid splashes Very likely By exposure to liquid splashes Likely By exposure to liquid splashes Not likely By exposure to liquid splashes Never By exposure to airborne particulate or suspended liquid aerosols By exposure to airborne particulate or suspended liquid aerosols Very likely By exposure to airborne particulate or suspended liquid aerosols Likely By exposure to airborne particulate or suspended liquid aerosols Not likely By exposure to airborne particulate or suspended liquid aerosols Never By contact with contaminated surfaces By contact with contaminated surfaces Very likely By contact with contaminated surfaces Likely By contact with contaminated surfaces Not likely By contact with contaminated surfaces Never Question Title * 7. Have you been in situations where your respirator was or potentially exposed to hazardous chemicals (if so identify the up to 5 chemicals to which you were exposed and length of exposure in minutes)? Chemical 1 and Duration (min) Chemical 2 and Duration (min) Chemical 3 and Duration (min) Chemical 4 and Duration (min) Chemical 5 and Duration (min) Question Title * 8. Given that only a finite number of chemicals can be selected, what strategy should be used for selecting test chemicals? Chemicals should be chosen to specific high priority inhalation hazards for first responders Chemicals should be chosen to represent a broad range of substances that are likely to permeate respirator materials A combination of approaches should be used Comments Question Title * 9. What priorities would you assign for the testing of the following chemicals or chemical types (high, moderate, low, not rated) Respiratory Hazard Dermal (skin) hazard Ammonia High risk Moderate risk Low risk Not rated Ammonia Respiratory Hazard menu High risk Moderate risk Low risk Not rated Ammonia Dermal (skin) hazard menu Chlorine High risk Moderate risk Low risk Not rated Chlorine Respiratory Hazard menu High risk Moderate risk Low risk Not rated Chlorine Dermal (skin) hazard menu Hydrogen cyanide High risk Moderate risk Low risk Not rated Hydrogen cyanide Respiratory Hazard menu High risk Moderate risk Low risk Not rated Hydrogen cyanide Dermal (skin) hazard menu Phosgene High risk Moderate risk Low risk Not rated Phosgene Respiratory Hazard menu High risk Moderate risk Low risk Not rated Phosgene Dermal (skin) hazard menu Chlorinated hydrocarbons (e.g., methyl chloride) High risk Moderate risk Low risk Not rated Chlorinated hydrocarbons (e.g., methyl chloride) Respiratory Hazard menu High risk Moderate risk Low risk Not rated Chlorinated hydrocarbons (e.g., methyl chloride) Dermal (skin) hazard menu Acid gases (e.g., hydrogen chloride, sulfuric acid) High risk Moderate risk Low risk Not rated Acid gases (e.g., hydrogen chloride, sulfuric acid) Respiratory Hazard menu High risk Moderate risk Low risk Not rated Acid gases (e.g., hydrogen chloride, sulfuric acid) Dermal (skin) hazard menu Regular hydrocarbons (e.g., hexane, toluene) High risk Moderate risk Low risk Not rated Regular hydrocarbons (e.g., hexane, toluene) Respiratory Hazard menu High risk Moderate risk Low risk Not rated Regular hydrocarbons (e.g., hexane, toluene) Dermal (skin) hazard menu Pesticide (e.g., parathion) High risk Moderate risk Low risk Not rated Pesticide (e.g., parathion) Respiratory Hazard menu High risk Moderate risk Low risk Not rated Pesticide (e.g., parathion) Dermal (skin) hazard menu Acrolein High risk Moderate risk Low risk Not rated Acrolein Respiratory Hazard menu High risk Moderate risk Low risk Not rated Acrolein Dermal (skin) hazard menu Acrylonitrile High risk Moderate risk Low risk Not rated Acrylonitrile Respiratory Hazard menu High risk Moderate risk Low risk Not rated Acrylonitrile Dermal (skin) hazard menu Dimethyl sulfide High risk Moderate risk Low risk Not rated Dimethyl sulfide Respiratory Hazard menu High risk Moderate risk Low risk Not rated Dimethyl sulfide Dermal (skin) hazard menu Question Title * 10. How would you rank the following factors in selecting test chemicals (rank top choice as 6, lowest choice as 1)? 1 2 3 4 5 6 N/A Inhalation (respiratory) hazard of chemical N/A 1 2 3 4 5 6 N/A Dermal (skin) exposure hazard of chemical N/A 1 2 3 4 5 6 N/A Ocular (eye) exposure hazard of chemical N/A 1 2 3 4 5 6 N/A Relative known permeation of chemical through respirator or respirator like materials N/A 1 2 3 4 5 6 N/A Likely frequency of exposure N/A 1 2 3 4 5 6 N/A Chemical physical properties that relate to likelihood of exposure (e.g., vapor pressure, vapor density) N/A Done